Synthesis, Characterization, and Structure of Tri-micron-halogeno- hexacarbonyldirhenate(I) Salts of Monocationic Porphyrin Acids

Abstract

The metal-carbonyl insertion method has been found useful for the preparation of bimetallic porphyrin complexes of rhodium, rhenium, and technetium. Metal carbonly halides are more reactive reagents than metal carbonyls for the synthesis of bimetallic complexes of porphyrins as well as bimetallic salts of porphyrin acids.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Mar 15, 1978
Accession Number
ADA052666

Entities

People

  • C. N. Morimoto
  • C. P. Hrung
  • D. L. Cullen
  • E. F. Meyer Jr
  • M. Tsutsui

Organizations

  • Texas A&M University

Tags

Communities of Interest

  • Air Platforms
  • Biomedical

DTIC Thesaurus Topics

  • Carbonyl Complexes
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Crystals
  • Diffractometers
  • Insensitive Explosives
  • Materials
  • Measurement
  • Military Research
  • New York
  • Scattering
  • Spectra
  • Spectroscopy
  • Standards
  • United States
  • X-Ray Diffraction

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry