Analytical Implications of Differential Pulse Polarography of Irreversible Reactions from Digital Simulation; Calculations and Experiments.

Abstract

Explicit finite difference simulations of differential pulse polarography have been developed for evaluating the analytical applications of differential pulse polarography to irreversible and quasireversible electron transfer reactions. From simulation data, detailed prediction of polarographic peak shape and position as a function of pulse height, pulse time and drop time is possible. Optimum conditions for analytical application of differential pulse polarography are discussed. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1978
Accession Number
ADA052836

Entities

People

  • James W. Dillard
  • John J. O'dea
  • R. A. Osteryoung

Organizations

  • Colorado State University

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Analytical Chemistry
  • California
  • Charge Transfer
  • Chemistry
  • Civil Engineering
  • Coefficients
  • Colorado
  • Diffusion Coefficient
  • Electrodes
  • Electron Transfer
  • Equations
  • Military Research
  • New York
  • Polarography
  • Simulations
  • Simulators
  • Standards

Fields of Study

  • Chemistry
  • Physics

Readers

  • Control Systems Engineering.
  • Electrochemical Surface Science
  • Radar Systems Engineering.

Technology Areas

  • Microelectronics