Structural and Dynamic Studies of Materials Possessing High Energy Content.
Abstract
The goal of this research is to provide a theoretical and experimental basis for the understanding of the properties of excited molecules and their emission characteristics. A particular emphasis has been directed toward the identification of chemiluminescent systems which might have the highest likelihood of providing a framework for the development of operating chemical lasers which emit in the visible spectral range. The thermal chemistry and photochemistry of dioxetanes and of valence isomers of benzene have been investigated. The chemistry of singlet oxygen is being explored to develop simple and convenient means of producing this species. An important development has been the discovery that the catalytic thermal generation of singlet oxygen from ground state (triplet) oxygen may be feasible. The possibility of using singlet oxygen in developing chemical lasers is also being explored. Finally, the mechanisms of electronic energy transfer and oxidation in polymers is being investigated with the goal of providing a fundamental understanding of these processes that will allow the systematic and rational development of strategies for stabilization of polymer systems.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 30, 1978
- Accession Number
- ADA052936
Entities
People
- Nicholas J. Turro
Organizations
- Columbia University