Accelerated Corrosion of Copper-Nickel Piping

Abstract

Unexpectedly severe corrosion occurred in cupro-nickel piping in seawater cooling systems aboard ships built in one location. A workshop, convened to discuss the problem, identified turbulence as a major contributing factor, and the practice of running the seawater loop wide open while throttling the fresh-water loop as contributory to the turbulence. Recommendations of the committee were: (1) reduce the velocity of flow in the pipes; (2) use long radius elbows whenever possible; and (3) conduct research of development to evaluate the following remedial measures--(a) suitability of alternate materials; (b) determination of the significance of the iron content in alloy 706 (90Cu-10Ni); (c) investigation of the relative corrosion rate when a negative potential is applied to the system, using the cupro-nickel piping as a cathode; (d) control of seawater pH to a value of about 9.0; and (e) use of electrochemical probes to detect changes in corrosion rates. The committee, in commenting on the Navy's research program, felt that the turbulence aspect had been given inadequate attention, that the role of ammonia had not been given adequate consideration, that the design of the shore-based simulation test did not sufficiently resemble the installed conditions, and that more should be done on characterizing reaction product films.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1977
Accession Number
ADA053083

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  • Ground and Sea Platforms

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  • California
  • Chemical Analysis
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  • Chemistry
  • Corrosion
  • Corrosion Resistance
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  • Materials Science
  • Metallurgy
  • Metals
  • Mining Engineering
  • New Jersey
  • Nitrogen Compounds
  • Oceanography
  • Standards

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  • Combustion and Flow Dynamics.
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