Studies of the Polymorphs of RDX.

Abstract

The primary purpose of this research has been to investigate the lattice and molecular dynamics of RDX by observing the effects of both slow and rapid heating on the vibrational modes of RDX, and to determine if a thermally induced phase transition to the unstable polymorph can be observed spectroscopically. A laser Raman investigation of octahydro-1-3-5-7-tetranitro-1-3-5-7-tetrazocine (HMX), the eight-member ring analog of RDX, has shown that thermally induced phase transitions can be observed and recorded with major, easily recognizable differences in the spectra of the different polymorphs. (Author)

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1978
Accession Number
ADA053155

Entities

People

  • Stephen T. Sergio

Organizations

  • University of Delaware

Tags

Communities of Interest

  • Air Platforms
  • Counter IED
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Synthesis
  • Chemistry
  • Crystal Lattices
  • Crystal Structure
  • Crystals
  • Diffraction
  • Equations Of State
  • Explosives
  • Heat Energy
  • Materials Science
  • Melting
  • Organic Chemistry
  • Phase Transformations
  • Rdx
  • Spectra
  • Spectroscopy
  • Transitions

Readers

  • Materials Science and Engineering.
  • Molecular Photonics/Laser Physics
  • Rocket Propulsion.

Technology Areas

  • Directed Energy