Absorption and Electronic Raman Scattering Spectra of the Gamma sub 8g State of IrF6 at 1.6 Micrometers - A Resolution of the Jahn-Teller Problem.
Abstract
Electronic Raman scattering and absorption spectra are presented which allow an interpretation of the vibronic structure of the Gamma sub 8g (2T sub 1g) excited electronic state of IrF6 at 1.6 micrometers. Large splittings and shifts are observed for the Jahn-Teller active nu2 (e sub g), nu5 (t sub 2g), and 2nu5 vibrations. From these spectra linear (D2 and D5) and quadratic (Q2(s sub 1g), Q2(e sub g), Q5(a sub 1g), Q5(e sub g), Q5(t sub 2g)) Jahn-Teller parameters can be determined. These data are compared with previously obtained parameters for the ReF6 ground state and the IrF6 Gamma sub 8g (2T sub 2g) at 0.6 micrometers. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Mar 01, 1978
- Accession Number
- ADA053553
Entities
People
- Elliot R. Bernstein
- J. D. Webb
Organizations
- Colorado State University