Cyclohexane Dehydrogenation of Clean Pd Surfaces Studied by UV Photoemission.

Abstract

Ultraviolet photoemission studies show that cyclohexane is adsorbed without decomposition on clean polycrystalline Pd and single crystal Pd(111) surfaces at low temperature (less than or equal to 120 K), but at 300 K it dehydrogenates to leave chemisorbed benzene on the surface. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jan 15, 1978
Accession Number
ADA054106

Entities

People

  • G. W. Rubloff
  • H. Luth
  • J. E. Demuth
  • W. D. Grobman

Organizations

  • IBM Thomas J. Watson Research Center

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Band Structures
  • Chemical Reaction Properties
  • Crystals
  • Cyclic Hydrocarbons
  • Cyclohexanes
  • D Band
  • Electrons
  • Energy Bands
  • Ionization
  • Ionization Potentials
  • Low Temperature
  • Measurement
  • Military Research
  • Photoelectric Emission
  • Polycrystals
  • Single Crystals
  • Work Functions

Readers

  • Organic Chemistry
  • Semiconductor Device Technology
  • Surface Coatings Technology.