Tetrametallic Nickel-Boron Clusters, (ETA to the 5th power-C5H5)4Ni4B4H4 and (ETA to the 5th power-C5H5)4Ni4B5H5, by transition metal aggregation on a small Borane framework

Abstract

The reaction of Na+B5H8- with nickelocene and sodium amalgam in tetrahydrofuran at ambient temperature yielded the title compounds, which were isolated as crystalline solids and characterized from their B11 and H FT NMR and mass spectra and an X-ray structure determination of the Ni4B4 cluster.

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Document Details

Document Type
Technical Report
Publication Date
May 01, 1978
Accession Number
ADA055400

Entities

People

  • James R. Bowser
  • Russell N. Grimes

Organizations

  • University of Virginia

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Analogs
  • Chemistry
  • Continents
  • Decoupling
  • Electrons
  • Geographic Regions
  • Geometry
  • Liquid Chromatography
  • Mass Spectra
  • Metals
  • Military Research
  • Spectra
  • Transition Metals
  • United States
  • United States Government
  • Virginia
  • X Rays

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry