The Effects of Physical and Chemical Processes on Two-Phase Detonations,

Abstract

Systematic studies of the effect of additives and fuel drop size on the detonability of heptane-air mixtures have been carried out under controlled laboratory conditions and in large scale field tests. It was shown in the shock tube studies that n-propyl nitrate and butyl nitrite as well as, to a lesser extent, small drop size can greatly widen the detonation limits and reduce initiation requirements of heptane-air mixtures. Large scale field tests of explosively disseminated fuel-air clouds confirm findings obtained in the laboratory tests, demonstrating that systematic laboratory tests can be used to predict detonability and performance of any new fuel system to be used in FAE munitions. Unique schlieren photographs of the reaction zone of propagating fuel-air detonations have been successfully obtained. No blast waves are observed either in the wave of single shocked fuel drops or from drops in the reaction zones of propagating detonations with air. Apparently, the assumption that such blast waves are necessary to maintain a two-phase detonation, is incorrect. Sensitized heptane is potentially superior to fuels used in current FAE munitions, providing increased explosive performance (larger area coverage per unit weight of fuel), greater safety in transport and handling and lower procurement costs.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1978
Accession Number
ADA056464

Entities

People

  • Barry Fishburn
  • Norman Slagg
  • Pai-lien Lu

Organizations

  • United States Army Armament Research, Development and Engineering Center

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Additives (Chemicals)
  • Blast Waves
  • Chemical Properties
  • Chemical Reactions
  • Chemistry
  • Combustion
  • Energy Transfer
  • Explosives
  • Field Tests
  • Fuel Additives
  • Fuel Air Explosives
  • Fuel Systems
  • Ignition
  • Ignition Lag
  • Internal Combustion Engines
  • Mass
  • Physical Properties

Readers

  • Combustion and Flow Dynamics.
  • Combustion science or combustion engineering.
  • Rocket Propulsion.