The Production of Decarborane-14 from Diborane by Laser Induced Chemistry,

Abstract

Pure B10H14 can be produced in high yields at room temperature by laser induced chemistry (LIC). No polymer (which is always present in pyrolysis) was observed when the laser power was kept below a certain threshold (10 W/sq cm for the CO2 laser). Also, the B5H11 product is always present in pyrolysis; yet never observed in LIC synthesis. This research demonstrates that LIC is a new viable area of chemistry that can be used for cost-effective synthesis of large poly-atomic molecules as well as smaller ones. Also, it demonstrates that LIC can be used in a prominent role for the synthesis of high energy binder molecules, burning rate modifiers and fuel additives with a substantial cost-savings.

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Document Details

Document Type
Technical Report
Publication Date
Jun 01, 1978
Accession Number
ADA056467

Entities

People

  • George A. Tanton
  • Harry C. Meyer
  • James A. Merritt
  • Raymond I. Greenberg

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Burning Rate
  • Carbon Dioxide Lasers
  • Cells
  • Chemical Lasers
  • Chemistry
  • Deuterium Fluoride Lasers
  • Fuel Additives
  • Infrared Spectra
  • Laser Beams
  • Lasers
  • Low Resolution
  • Melting Point
  • Pyrolysis
  • Radiation
  • Solid Propellants
  • Spectra

Fields of Study

  • Chemistry
  • Physics

Readers

  • Electrical Engineering
  • Molecular Photonics/Laser Physics
  • Organic Chemistry

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers