Synthesis and Characterization of the Mixed-Metal Alkylidyne Clusters RCFeCo2(CO)9H (R = CH3, C2H5, C6H5).
Abstract
Reaction of closed metal carbonyl trimers with carbonylmetalates has been shown to be a useful synthetic route to tetranuclear clusters in which the carbonylmetalate adds to the face of the original trimer. This type of reaction has been particularly useful for the synthesis of mixed-metal clusters. In principle, clusters with more than four framework atoms could be prepared by the addition of carbonylmetalates to the triangular faces of tetranuclear and larger clusters.
Document Details
- Document Type
- Technical Report
- Publication Date
- Jul 29, 1978
- Accession Number
- ADA058229
Entities
People
- Gregory L. Geoffroy
- Howard W. Withers
- Ronald A. Epstein
Organizations
- Pennsylvania State University