Rational Synthesis of Unidimensional Mixed Valence Solids. Structure-Oxidation State-Charge Transport Relationships in Iodinated Nickel and Palladium Bisbenzoquinonedioximates.

Abstract

The results of the present investigation indicate that the M(bqd)2I(0.50) materials, M = Ni, Pd, are best formulated as M(bqd)2I(0.50).S materials where S represents various amounts of the aromatic solvent employed for crystallization. As deduced from resonance Raman, I-129 Mossbauer, and diffuse x-ray scattering measurements, the iodine is present as I3-, and thus the m(bqd)2I(0.50).S materials are indeed partially oxidized.

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Document Details

Document Type
Technical Report
Publication Date
Aug 22, 1978
Accession Number
ADA059642

Entities

People

  • Davida Webster Kalina
  • Leo D. Brown
  • Malcolm S. Mcclure
  • Stanley L. Ruby
  • Steven Schultz

Organizations

  • Northwestern University

Tags

Communities of Interest

  • Air Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemistry
  • Crystal Structure
  • Crystals
  • Diffraction
  • Electrical Conductivity
  • Mass Spectrometry
  • Military Research
  • Physics
  • Reflection
  • Scattering
  • Spectra
  • Spectroscopy
  • United States
  • Universities
  • X Ray Scattering
  • X Rays
  • X-Ray Diffraction

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  • Organic Chemistry
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