Synthesis and NMR Study of Ethyl- and Perfluoro-ethyltin Vinyl and Hydride Derivatives,
Abstract
The syntheses of four perfluorethyltin compounds are reported for the first time via a Barbier reaction from the corresponding ethyl- and vinyltin bromides. The synthetic reactions resulted in the iodide transhalogenation product in the ethyltin case and the vinyl group redistribution product in the vinyltin case as well as the expected products. The new compounds were characterized by infrared and mass spectral data, and studied by proton and fluorine-19 nmr.
Document Details
- Document Type
- Technical Report
- Publication Date
- Aug 16, 1978
- Accession Number
- ADA059707
Entities
People
- Jerold J. Zuckerman
- S. E. Ulrich
Organizations
- University of Oklahoma