A Chemical Singlet Molecular Oxygen Generator.

Abstract

A method of generating a continuous wave (cw) 'clean' stream of oxygen containing a large fraction in the singlet state has been developed based upon the base catalyzed chemical reaction of chlorine fluorosulfate and hydrogen peroxide. After the addition of molecular iodine a fast energy transfer process between O2 and I created a population inversion between the spin-orbit states of atomic iodine. This population inversion was directly observed in an optical double resonance experiment in which the excited spin-orbit state population was decreased as the transition was driven toward saturation by a pulsed iodine atom laser. The O2 generator, quantitative diagnostics, optical double resonance experiment, and lasing attempts are described in this report. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1978
Accession Number
ADA062091

Entities

People

  • A. T. Pritt
  • D. Pilipovich
  • I. B. Goldberg
  • R. D. Coombe
  • R. I. Wagner

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Angle Of Incidence
  • Chemical Reactions
  • Decomposition
  • Detectors
  • Energy Transfer
  • Flow Rate
  • Laser Resonators
  • Lasers
  • Losses
  • Measurement
  • Optomechanics
  • Partial Pressure
  • Physics Laboratories
  • Pressure Distribution
  • Reflection
  • Resonance
  • Vapor Pressure

Fields of Study

  • Physics

Readers

  • Optical Physics and Photonics.
  • Organic Chemistry
  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Space
  • Space - Hall-Effect Thruster