Studies on Evaporation of Hydrazine and Procedures for Cleanup of Small Spills

Abstract

The evaporation rates of hydrazine (N2H4) from pools of the neat fuel and from aqueous solutions were measured under various environmental conditions. Hydrazine continues to evaporate for long periods of time (several days) even from solutions as dilute as 25-percent N2H4. Solutions of hydrazine appear to absorb carbon dioxide from the atmosphere. Carbon dioxide gas also suppresses evaporation of hydrazine from concrete surfaces. Procedures are outlined for cleanup and decontamination of small spills of hydrazine in the flightline area. Calcium hypochlorite (HTH), sodium hypochlorite solution (household bleach), and hydrogen peroxide with copper catalyst were evaluated for use as possible oxidants to treat dilute hydrazine solutions. Although all three give satisfactory results, either HTH or household bleach is recommended because of availability and ease of use.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1978
Accession Number
ADA064675

Entities

People

  • Arland W. Eyl Jr.
  • Thomas B. Stauffer

Tags

Communities of Interest

  • Biomedical
  • Ground and Sea Platforms
  • Human Systems
  • Weapons Technologies

DTIC Thesaurus Topics

  • Air Force
  • Aircrafts
  • Aqueous Solutions
  • Availability
  • Carbon Dioxide
  • Catalysts
  • Chemical Synthesis
  • Chemistry
  • Chlorine
  • Containers
  • Liquids
  • Materials
  • Medical Personnel
  • Rocket Oxidizers
  • Sodium Compounds
  • Time Intervals
  • Vapors

Fields of Study

  • Environmental science

Readers

  • Combustion science or combustion engineering.
  • Environmental Engineering.
  • Petroleum Engineering