Synthesis of the Plasma Chemistry Occurring in High Power CO2 Lasers

Abstract

The neutral chemistry of the following mixtures have been studied by using a quadrupole mass spectrometer and a theoretical model: CO2/Ar, N2/Ar, CO2/N2/Ar, CO2/He/Ar, and CO2/N2/He/Ar. Co2 dissociation occurs by direct electron impact and appears to depend on initial CO2 concentration and mixture. Very little N2 dissociation occurs in a pure N2 discharge; however, dissociation of N2 increases when it is added to a mixture containing CO2. This dissociation is less than 1%. Consequently, the dominant nitrogen oxide in mixtures containing CO2 and N2 is NO, and the concentration of NO never exceeds 1%. The species CHO and CH2O are present at high discharge currents if there is a small amount of water contamination in mixtures containing CO2.

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1978
Accession Number
ADA064756

Entities

People

  • David E. Toodle

Organizations

  • Air Force Institute of Technology

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Amplifiers
  • Carbon Dioxide Lasers
  • Charged Particles
  • Chemical Reactions
  • Chemistry
  • Detectors
  • Differential Equations
  • Dissociation
  • Electric Discharges
  • Electron Energy
  • Electrons
  • Flow Rate
  • Lasers
  • Mass Spectrometers
  • Measurement
  • Nitrogen Oxides
  • Spectrometers

Readers

  • Combustion science or combustion engineering.

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Microelectronics