Analysis of Pressure Producing Reactions in Lithium-Sulfur Dioxide Cells.

Abstract

Although the State-of-the-Art hermetically sealed high-rate D cells made by P.R. Mallory and Co. Inc. are sufficiently abuse resistant for many applications, this program was initiated to explore the feasibility of improving the intrinsic abuse resistance of the system even further by chemical and/or mechanical means, so that the product may be rendered Safe under all user conditions. The approach that was pursued involved: (a) the identification of the chemical reactions responsible for the pressure buildup and/or thermal runaway, (b) the determination of the sensitivity of these reactions to the various use and abuse variables, and (c) the development of methods to desensitize these reactions.

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Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1979
Accession Number
ADA064977

Entities

People

  • A. N. Dey
  • R. W. Holmes

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Carbon
  • Carbonate Esters
  • Chemical Reactions
  • Chemistry
  • Dielectric Gases
  • Differential Thermal Analysis
  • Energy
  • Exothermic Reactions
  • Films
  • Filter Paper
  • Heat Energy
  • Heat Of Activation
  • High Temperature
  • Materials
  • Melting Point
  • Nitriles
  • Thermal Analysis

Fields of Study

  • Chemistry

Readers

  • Adaptive Control and Estimation with Uncertainty in Dynamic Systems.
  • Battery Technology and Engineering
  • Electrochemical Engineering/ Fuel Cell Technologies