Non-Wetting Materials for Fabrication of Fuel Cell Electrodes.

Abstract

A study of propane electrooxidation on a platinum coated ion exchange membrane was conducted in both 85% phosphoric acid and trifluoromethanesulfonic acid monohydrate (TFMSA). The phosphoric acid system's propane electrooxidation currents were characterized with respect to temperature, propane flow rate and oxidation potential. Then, the propane electrooxidatin currents of the TFMSA system were determined and compared to the phosphoric acid system. The steady state currents in the TFMSA solvent were two times greater than in the 85% H3PO4 acid solvent. Steady state hydrogen electrooxidation current measurements were made in both solvents and compared to the propane electrooxidation currents to estimate the practicability of propane electrooxidation. On a mole basis, the propane currents were 1/143 of the hydrogen currents. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1977
Accession Number
ADA066602

Entities

People

  • Robert Mack
  • Stanley Bruckenstein

Organizations

  • University at Buffalo

Tags

Communities of Interest

  • Energy and Power Technologies
  • Space

DTIC Thesaurus Topics

  • Abstracts
  • Acids
  • Chemical Synthesis
  • Chemistry
  • Combinatorial Analysis
  • Current Density
  • Electrodes
  • Flow Rate
  • Fuel Cells
  • Gas Flow
  • Generators
  • Ion Exchange
  • Materials
  • Membranes
  • New York
  • Phosphoric Acids
  • Three Dimensional

Fields of Study

  • Chemistry

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies

Technology Areas

  • Biotechnology
  • Biotechnology - Bioremediation