Mechanistic Aspects of 1,2-Dialkyldimolybdenum (M=M) Chemistry.
Abstract
Both historically and commercially alpha-alkyl complexes have played a prominent role in the development of mononuclear transition metal chemistry. The recent syntheses and characterizations of 1,2-dialkyl-dimolybdenum and -ditungsten compounds afford the opportunity of studying the reactivity patterns of alpha-alkyl groups bonded to the simplest of metal clusters, namely dimetal centers. We wish here to report the results of labelling studies using the alpha-CH2CD3 ligand and furthermore to address ourselves to the mechanistic implications of these results.
Document Details
- Document Type
- Technical Report
- Publication Date
- Apr 18, 1979
- Accession Number
- ADA067868
Entities
People
- Deborah A. Haitko
- Malcolm H. Chisholm
Organizations
- Indiana University