Synthesis of New Gem-Dialkyltetrachlorophosphazenes via 'Metallophosphazene' Intermediates.

Abstract

The reaction of hexachlorocyclotriphosphazene with organocopper reagents leads to the synthesis of a highly reactive phosphazene-copper intermediate. This intermediate reacts with alkyl halides to yield a range of hitherto inaccessible alkylphosphazenes, including several with unsaturated alkyl side groups. These cyclic oligomer reactions are model systems for the analogous high polymers. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Apr 26, 1979
Accession Number
ADA068949

Entities

People

  • Harry R. Allcock
  • Paul J. Harris

Organizations

  • Pennsylvania State University

Tags

Communities of Interest

  • Ground and Sea Platforms
  • Materials and Manufacturing Processes
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkynes
  • California
  • Chemical Synthesis
  • Chemistry
  • Engineering
  • Grignard Reagents
  • Halogenated Hydrocarbons
  • Marine Corps
  • Military Research
  • New York
  • Pennsylvania
  • Phosphazene
  • Reagents
  • United States
  • United States Government
  • Universities

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry