Infrared Optical Properties of Bipropellant Cryocontaminants

Abstract

The infrared spectral transmittance of cryofilms formed by MMH, N2O4, and N2H4 propellants was measured. These films were cryopumped on 20 and 77K germanium substrates and ranged in thickness from 0.25 to 9 microns; the deposition pressure for the films was approximately 1 x 10-7 torr. Transmission spectra were obtained for the 500 to 3700 wavenumber range using a Fourier transform spectrometer. Values of the complex index of refraction for the cryodeposits were derived from the experimental data using an analytical model and a nonlinear least-squares method. The analytical model treats the germanium as a thick, noninterfering film and the deposit as a thin film. Results from the least-squares method are also compared with a Kramers-Kronig determination of the real part of the index of refraction. The optical properties of such cryofilms are essential for predicting the degradation of cryocooled optical surfaces contaminated by liquid propellant exhaust plumes.

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Document Details

Document Type
Technical Report
Publication Date
Aug 01, 1979
Accession Number
ADA073186

Entities

People

  • A. Matthew Smith
  • Bobby E. Wood
  • J. A. Roux

Organizations

  • Arnold Engineering Development Complex

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Sensors
  • Space

DTIC Thesaurus Topics

  • Air Force
  • Helium Neon Lasers
  • Infrared Spectra
  • Materials
  • Materials Laboratories
  • Materials Science
  • Measurement
  • Optical Phenomena
  • Optical Properties
  • Propellants
  • Quartz Crystal Microbalances
  • Refraction
  • Refractive Index
  • Rocket Oxidizers
  • Spectra
  • Three Dimensional
  • Two Dimensional

Fields of Study

  • Physics

Readers

  • Spectroscopy.
  • Thin Film Deposition Science.