The Crystal Structure and Variable Temperature 119m Sn Moessbauer Study of Trimethyltin Glycinate, A One-Dimensional, Amino-Bridged Polymer.
Abstract
The crystal structure of trimethyltin glycinate has been determined by Patterson Fourier techniques to a final 'R'-factor of 0.066 for 1103 unique reflections. The crystals are tetragonal with space group P41 or P43 with a = b = 7.839(9) and c = 14.659(11)Angstom, Z = 4, and are composed of stacks of linearly polymeric trimethyltin glycinate molecules bridged axially at tin through the amino nitrogen atoms of the amino acid. There is hydrogen bonding between carbonyl oxygen and amino group N-H moieties along the chains and between the chains to produce a perpendicular weave of one-dimensional polymer threads.
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 04, 1979
- Accession Number
- ADA074383
Entities
People
- B. Y. K. Ho
- F. Reidinger
- J. A. Zubieta
- Jerold J. Zuckerman
- K. C. Molloy
Organizations
- University of Oklahoma