Phosphoric Acid Derivatives of Tin. II. The Crystal and Molecular Structure of 0,0'-Diethyldithiophosphatotriphenyltin(IV) at 138K. A Unique Monodentate Dithiophosphate Derivative.
Abstract
O, O-Diethyldithiophosphatotriphenyltin(IV), C22H25O2S2Sn, crystallizes in the triclinic space group P1. The structure was determined by the heavy atom technique from 4838 reflections measured at 138 + or - 2K on an automatic difffractometer using monochromated Mo-K(alpha) radiation, to a final R-value of 0.039. The molecule contains a four-coordinate tin atom and a monodentate dithiophosphate ligand, the first such example of a dithiophosphate ligand which is neither chelating nor bridging.
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 10, 1979
- Accession Number
- ADA074588
Entities
People
- D. Van Der Helm
- Jerold J. Zuckerman
- K. C. Molloy
- M. B. Hossain
Organizations
- University of Oklahoma