Pseudopolarographic Determination of Metal Complex Stability Constants in Dilute Solution by Rapid Scan Anodic Stripping Voltammetry.

Abstract

By using a computer controlled anodic stripping voltameter with automatic background correction, pseudopolarograms can be obtained by plotting the peak area vs. the deposition potential for a series of stripping voltametric runs. With ASV as a method of amplification, the ligand number and stability constants are determined for metal complexes at concentration ranges expected of natural water systems. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1979
Accession Number
ADA074806

Entities

People

  • Bruce R. Kowalski
  • Steven D. Brown

Organizations

  • University of Washington

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Analytical Chemistry
  • Carbonates
  • Chemical Compounds
  • Chemistry
  • Chlorides
  • Coordination Complexes
  • Electrodes
  • Equations
  • Materials
  • Materials Science
  • Measurement
  • Polarography
  • Reversible
  • Speciation
  • Spectroscopy
  • Voltammetry
  • Waves

Fields of Study

  • Chemistry

Readers

  • Electrochemical Surface Science
  • Geodesy