Preparation and Properties of ((Trimethylsilyl)-methyl)-gallium(III) Compounds.

Abstract

A series of neutral organogallium(III) compounds which incorporate the (trimethylsilyl)methyl ligand, Ga(CH2SiMe3)n X3-n (n = 3,2,1; X = (Cl, Br) have been prepared and fully characterized by elemental analyses NMR and infrared spectroscopy, molecular weight data, solubility properties and Lewis acid-base chemistry. The parent compound Ga(CH2SiMe3)3 was prepared from GaCl3 by a standard Grignard reaction in diethylether. The halogen derivatives were prepared from Ga(CH2SiMe3)3 by elimination reactions with HCl or HBr and exchange reactions with GaCl3 or GaBr3.

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1979
Accession Number
ADA076123

Entities

People

  • O. T. Beachley Jr.
  • R. G. Simmons

Organizations

  • University at Buffalo

Tags

Communities of Interest

  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Chemical Properties
  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Chlorine
  • Elimination Reactions
  • Exchange Reactions
  • Grignard Reactions
  • Halogen Compounds
  • Halogens
  • Infrared Spectra
  • Military Research
  • New York
  • Physical Properties
  • Plastic Explosives
  • Spectra

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry

Technology Areas

  • Microelectronics