Formation of Porous Films on Titanium Alloys by Anodization Treatments

Abstract

This investigation is part of a program which looks at the effects of surface treatments on surface chemistry and morphology of titanium and titanium alloys. This part considers the effect of surface treatments on the alloy titanium-6 aluminum-4 vanadium which use anodization to produce a porous oxide film. Porous anodized films on titanium alloys have shown to be advantageous for adhesive bonding and other purposes. Porosity may be achieved by increasing current density in the anodization bath by increasing the voltage, increasing the concentration of the electrolyte, increasing the temperature, or adding current carrying ions to the electrolyte. In this work, experiments are described in which each of the methods for increasing current density are accomplished. Characterization results on the surfaces of these anodized oxides are shown using scanning electron microscopy, ion scattering spectrometry, secondary ion mass spectrometry, and Auger electron spectrometry. Addition of lithium nitrate to phthalic acid electrolytes causes porosity in anodized films, but the lithium ions do not enter the oxide film.

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1979
Accession Number
ADA077676

Entities

People

  • W. L. Baun

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Adhesives
  • Air Force
  • Air Force Facilities
  • Auger Electrons
  • Chemical Synthesis
  • Chemistry
  • Mass Spectra
  • Mass Spectrometry
  • Materials
  • Materials Laboratories
  • Oxide Films
  • Spectra
  • Spectrometry
  • Spectroscopy
  • Surface Chemistry
  • Titanium
  • Titanium Alloys

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Surface Coatings Technology.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene