VPE Growth of (Al, Ga)As.

Abstract

The organometallic vapor phase epitaxial (OMVPE) growth process was utilized for the growth of Alx Ga1-x As alloys in both hot wall and cold wall reactor systems. Growth parameters including substrate temperature, V/III ratio, flow ratio, etc. were studied together with their influence on the electrical transport and luminescent properties of the epitaxial layers. Both p-type (Zn)and n-type (Te) dopants were used to achieve the desired doping profiles. Carbon and oxygen were found to be significant contaminants in these layers and two approaches to minimizing their concentration were studied. In the hot wall system HCl was added to the gas stream; in the cold wall system the use of graphite baffles was found to reduce the concentration of non-radiative centers. The photoluminescence efficiency of layers grown under optimized conditions were found to be comparable to that of LPE layers. Deep level transient spectroscopy (DLTS) measurements revealed two characteristic levels at approximately 0.41 eV and 0.49 eV respectively, with a weak dependence on compositions. Double heterostructure lasers were successfully fabricated from these layers and exhibited threshold current densities within a factor of 2 of layers of the same geometry using LPE material. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Oct 01, 1979
Accession Number
ADA078264

Entities

People

  • Gerald B. Stringfellow

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Band Gaps
  • Band Structures
  • Crystal Lattice Vibrations
  • Crystal Structure
  • Crystals
  • Current Density
  • Electrons
  • Energy Bands
  • Epitaxial Growth
  • Free Energy
  • Materials
  • Partial Pressure
  • Scattering
  • Semiconductors
  • Spectra
  • Spectroscopy
  • Thermodynamics

Fields of Study

  • Materials science

Readers

  • Combustion and Flow Dynamics.
  • Semiconductor Device Technology

Technology Areas

  • Directed Energy
  • Directed Energy - Lasers
  • Directed Energy - Pulsed-Laser Deposition