The Preparation of Some Novel Electrolytes: Synthesis of Partially Fluorinated Alkanesulfonic Acids as Potential Fuel Cell Electrolytes.

Abstract

The objective of this research was to prepare some strong acids for evaluation by Fort Belvoir as potential fuel cell electrolytes. The major acid, other than phosphoric, H3PO4, currently under investigation by Fort Belvoir as a fuel cell electrolyte is TFMSA, CF3SO3H.H2O, trifluoromethanesulfonic acid monohydrate aqueous solutions and sodium salt mixtures. TFMSA has been found to be superior to H3PO4 from the standpoint of electrode kinetics, but certain undesirable characteristics (volatility; wetting of Teflon) led to this research for a better fuel cell electrolyte.

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Document Details

Document Type
Technical Report
Publication Date
Sep 01, 1979
Accession Number
ADA078473

Entities

People

  • C. Bunyagidj
  • H. Pietrowska
  • M. H. Aldridge

Organizations

  • American University

Tags

Communities of Interest

  • Advanced Electronics
  • Counter IED
  • Energy and Power Technologies
  • Materials and Manufacturing Processes
  • Space

DTIC Thesaurus Topics

  • Alkenes
  • Aqueous Solutions
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Chlorination
  • Chlorine
  • Dermatologic Agents
  • Electronics Laboratories
  • Energy
  • Engineering
  • Ethers
  • Fuel Cells
  • Halides
  • Hydrogen
  • Ions
  • Sulfonic Acids

Fields of Study

  • Materials science

Readers

  • Electrochemical Engineering/ Fuel Cell Technologies
  • Petroleum Engineering

Technology Areas

  • Biotechnology