Catalytic Oxidation of Phosphines by Transition Metal-Activated Carbon Dioxide.

Abstract

The complexes (Ph3P) 3RhCl and (cyclooctene) 2RhCl 2 have been found to catalyze the oxidation of phosphines by carbon dioxide in refluxing decalin. The rate of oxidation increases in the order PPh3 less than PBuPh2 less than PEt3. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Nov 19, 1979
Accession Number
ADA079644

Entities

People

  • Kenneth M. Nicholas

Organizations

  • Boston College

Tags

DTIC Thesaurus Topics

  • Alternative Fuels
  • Carbon Dioxide
  • Catalytic Oxidation
  • Chemical Synthesis
  • Chemistry
  • Coordination Complexes
  • Metals
  • Military Research
  • Molecular Sieves
  • Oxidation
  • Oxides
  • Phosphine
  • Phosphine Oxides
  • Transition Metals
  • Transitions
  • United States Government

Fields of Study

  • Chemistry

Readers

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