Thermal Outgassing of DC 93-500, a TWT Encapsulant

Abstract

The silicone traveling wave tube (TWT) encapsulant DC 93-500 has been subjected to thermal/vacuum analyses to verify its thermal stability and determine the extent of outgassing at the most severe expected operating conditions. Some limited comparisions have been made with a potential substitute encapsulant, Sylgard-184. The thermal stability of 93-500 is entirely satisfactory under the conditions studied (120 C, vacuum, long term). Significant outgassing was detected. Sufficient characterization was carried out to identify the mechanism of outgassing as being due to hydrolysis of silane by residual water in 93-500 base resin. The reaction produces volatile mono-vinyl silanol with appreciable quantities of hydrogen as a byproduct. The possible influence of the outgassing on the ultimate mechanical properties is discussed, as well as the potential for contamination of adjacent optical surfaces, and the possibility of the reaction as a source of hydrogen within the tubes. Firm answers to the additional questions raised by this study are not presently available. (Author)

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Sep 30, 1979
Accession Number
ADA079745

Entities

People

  • C. A. Gaulin
  • M. Buechler
  • V. L. Knight

Organizations

  • The Aerospace Corporation

Tags

Communities of Interest

  • Space

DTIC Thesaurus Topics

  • Air Force
  • Body Weight
  • Boiling Point
  • Curing Agents
  • Failure Mode And Effect Analysis
  • Hydrogen
  • Hydrolysis
  • Mass Spectra
  • Materials
  • Mechanical Properties
  • Outgassing
  • Physical Properties
  • Residuals
  • Spectra
  • Thermal Stability
  • Traveling Wave Tubes
  • Traveling Waves

Readers

  • Electronics Engineering
  • Polymer Science and Engineering.
  • Theoretical Analysis.