Basic Studies Relative to the Syntheses of Unsymmetrical Dimethylhydrazine and Monomethylhydrazine by Chloramination

Abstract

The reactions of chloramine with appropriate nitrogen bases to form unsymmetrical dimethylhydrazine or monomethylhydrazine were examined. Various by-products were identified and mechanisms proposed. Processes for the synthesis of both of these hydrazines were developed. The oxidation of unsymmetrical dimethylhydrazine by gaseous oxygen was studied and the various products identified. The oxidation of monomethylhydrazine was also investigated. The oxidation of unsymmetrical dimethylhydrazine by mercuric oxide was also studied. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Dec 07, 1979
Accession Number
ADA079985

Entities

People

  • Harry H. Sisler

Organizations

  • University of Florida

Tags

Communities of Interest

  • Energy and Power Technologies
  • Ground and Sea Platforms
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption
  • Alcohols
  • Amines
  • Chemical Reaction Properties
  • Chemical Synthesis
  • Chemistry
  • Chromatographic Analysis
  • Crystal Structure
  • Hydrazines
  • Infrared Spectra
  • Mass Spectra
  • Mass Spectrometry
  • Measurement
  • Organic Chemistry
  • Rate Of Formation
  • Spectra
  • Spectroscopy

Readers

  • Organic Chemistry
  • Underwater engineering and Marine Technology.