The Implantation of Impurity Ions and Proton Bombardment in Indium Phosphide.

Abstract

Ion Implantation of InP has been studied from qualification of substrates through characterization of the electrical transport properties of the resulting layers. InP(Fe) is found to have sufficient resistivity for typical device applications in contrast to InP(Cr). Residual damage from grit polishing compromised mobility and activation efficiency; a bromine-methanol etch polish yields superior surfaces and reduced residual damage. This etch-polish reveals either FeP precipitates or In inclusions in available InP(Fe) wafers. In contrast to GaAs(Cr), InP(Fe) has never exhibited anomalous compensation or conversion phenomena. Qualification consists of eliminating ingots with excessive precipitate or inclusion counts; consistent activation and mobility data are achieved using only this qualification. Acceptable activation and mobility can be achieved via 700 C annealing. Phosphosilicate glass deposited by the CVD technique provides effective encapsulation to this temperature. Undoped SiO2 fails due to stress and phosphorous absorption problems. Plasma deposited Si3N4 is effective to more than 750 C but it results in a shallow n(+) conversion layer presumably due to indiffusion of excess Si from the Si3N4.

Document Details

Document Type
Technical Report
Publication Date
Aug 31, 1979
Accession Number
ADA080144

Entities

People

  • G. W. Eldridge

Tags

DTIC Thesaurus Topics

  • Alcohols
  • Coatings
  • Contrast
  • Conversion
  • Encapsulation
  • Implantation
  • Inclusions
  • Ion Implantation
  • Ions
  • Methanols
  • Mobility
  • Polishes
  • Precipitates
  • Proton Bombardment
  • Qualifications
  • Residuals
  • Transport Properties

Fields of Study

  • Materials science

Readers

  • Semiconductor Device Technology
  • Surface Coatings Technology.