Synthesis and Structure of a New Class of Metallophthalocyanato (pyridine or THF) - Ruthenium(II) and carbonylphthalocyanato (pyridine or THF)osmium(II).

Abstract

Carbonylphthalocyanato(pyridine)ruthenium(II) PcRu(CO) (Py), carbonylphthalocyanatopyridineosmium(II) PcOs(CO) (Py), and carbonylphthalocyanato (tetrahydrofuran)ruthenium(II) PcRu(CO) (THF) were prepared in pure form. They are among the first reported metallophthalocyanines with a carbonyl as one of their axial ligands. Furthermore, several new ways of synthesizing these complexes in quantitative yields have been established. The structure of PCOs(CO) (Py) were elucidated by the X-ray diffraction analysis. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1980
Accession Number
ADA080167

Entities

People

  • M. Tsutsui
  • Shuichi Omiya

Organizations

  • Texas A&M University

Tags

DTIC Thesaurus Topics

  • Carbon Monoxide
  • Carbonyl Complexes
  • Chemical Synthesis
  • Chemistry
  • Chlorides
  • Column Chromatography
  • Dielectric Gases
  • Diffraction
  • Diffraction Analysis
  • Diffractometers
  • Infrared Spectra
  • Inorganic Chemistry
  • Organic Chemistry
  • Scattering
  • Spectra
  • Universities
  • Visible Spectra

Fields of Study

  • Chemistry

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  • Organic Chemistry