Investigation of Methods to Eliminate Voltage Delay in Li/SOCl2 Cells.

Abstract

The rate of growth of passivating films on lithium in SOCl2 and 1.8 M LiAlCl4/SOCl2 electrolyte has been measured by weight gain of stored lithium samples, and by pulse polarization measurements on stored cells. The film on lithium when measured in this way was found to be much thicker than when calculated from capacitance measured by pulse polarization. Micropolarization and capacitance measurements of lithium stored in 0.25 M Li2B10Cl10/SOCl2 have indicated that the film formed in this electrolyte is much thinner than that formed in 1.8 M LiAlCl4/SOCl2. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Nov 01, 1979
Accession Number
ADA080194

Entities

People

  • Carl R. Schlaikjer
  • Clifton A. Young
  • Marc S. Dobrusin

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Body Weight
  • Capacitance
  • Chemistry
  • Corrosion
  • Electrodes
  • Electrolytes
  • Electron Microscopes
  • Electrons
  • Free Radicals
  • Instrumentation
  • Materials
  • Measurement
  • Metals
  • Physical Properties
  • Spectra
  • Thickness
  • Visible Spectra

Readers

  • Electrical Engineering
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Thin Film Deposition Science.