Preparation and Photoelectronic Properties of FeNbO4.
Abstract
The orthorhombic alpha-PbO2 phase of FeNbo4 was prepared and its photo-electronic properties measured: Sintered disks were shown to be n-type and gave a conductivity of 40 ohm-cm. Measurements of the photoresponse gave a flat-band potential between 0.1 and 0.4 V vs SCE at a pH of 8.5 and an optical band gap of 2.08(2) eV. Several higher-energy band gaps at 2.68(2), 2.94(2), 3.24(2) and 4.38(2) eV were also determined. There appears to be an enhancement of the quantum efficiency due to the presence of Fe06 active centers while retaining the fundamental characteristics of the (NbO6) octahedra. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Jan 17, 1980
- Accession Number
- ADA080247
Entities
People
- Aaron Wold
- Bijan Khazai
- Jacob Hormadaly
- John Koenitzer
- Kirby Dwight
Organizations
- Brown University