Comparative Raman Study of Mixed-Alkali and Similar Ion Exchanged Glasses.

Abstract

The Raman spectra of analogous ion exchanged and mixed alkali disilicate and aluminodisilicate glasses of the same relative composition of dissimilar cations have been determined and employed to investigate the origin of the similarity of the mechanical loss features exhibited by them. Ion exchange of Na+ for Li+ in Li2O-Al2O3-2SiO2 glasses is shown to yield glasses whose network structure is different from that of the mixed alkali glasses of the same stoichiometry, but to attain that structure upon annealing. The network structure of ion exchanged and conventionally mixed alkali disilicate glasses are apparently identical. These results are interpreted in light of the mechanical loss spectra of the analogous glasses prepared in the two ways. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Dec 10, 1979
Accession Number
ADA080840

Entities

People

  • Charles Windisch
  • William M. Risen Jr

Organizations

  • Brown University

Tags

Communities of Interest

  • Advanced Electronics
  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Alkali Glass
  • Chemical Engineering
  • Chemistry
  • Composite Materials
  • Crystal Structure
  • Engineering
  • Frequency
  • Glass Fibers
  • Internal Friction
  • Ion Exchange
  • Materials
  • Materials Laboratories
  • Materials Science
  • Mechanical Properties
  • Military Research
  • Raman Spectra
  • Spectra

Readers

  • Materials Science and Engineering.
  • Theoretical Analysis.