Failure Mechanisms and Interphase Chemistry of Gold Films on Ti6Al4V. Part I. Surface Chemistry of Failure Surfaces.

Abstract

This work is part of a program which looks at the effects of surface treatments on surface chemistry and morphology of titanium alloys with reference to adhesive bonding. Here gold is vapor deposited on Ti6Al4V which was prepared to simulate conditions of etching and aging which might be encountered during processing and use. Although this model system of gold on Ti6Al4V is not a direct analogy to adhesive bonding, certain similarities do exist and the system provides interesting information on bond failure mechanisms. Surface chemical analysis using ISS/SIMS showed that the gold on titanium alloy could model the failure mechanisms on surfaces prepared by methods similar to that in adhesive bonding. ISS/SIMS was found to be a sensitive chemical method to determine locus of failure and the change of composition at interfaces following humid aging and bond testing. Several types of failures appeared to be observed. Fractures which appeared to have occurred by interfacial failure were actually found to be mixed mode failures or failures in a weak boundary layer.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1980
Accession Number
ADA081727

Entities

People

  • W. L. Baun

Organizations

  • Air Force Research Laboratory

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Adhesion
  • Adhesive Bonding
  • Adhesives
  • Air Force
  • Air Force Facilities
  • Boundary Layer
  • Chemical Analysis
  • Chemistry
  • Elements
  • Mass Spectrometry
  • Materials
  • Materials Laboratories
  • Materials Science
  • Mechanics
  • Surface Chemistry
  • Titanium
  • Titanium Alloys

Readers

  • Reinforced Composite Materials
  • Theoretical Analysis.
  • Thin Film Deposition Science.