New Functional Allylic Lithium Reagents: Gem-Dialkoxyallyllithium Reagents: A Useful Route to beta-Silyl and b-Stannylpropionate Esters,

Abstract

The reaction of sec-butyllithium with acrolein dialkyl acetals in THF or in THF/Et2O/pentane at -95 C results in formation of gem-dialkoxyallyllithium reagents, Li(CH2CHC(OR))2.

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1979
Accession Number
ADA081936

Entities

People

  • Dietmar Seyferth
  • Helmut A. Klein
  • Robert E. Mammarella

Organizations

  • Massachusetts Institute of Technology

Tags

Communities of Interest

  • Advanced Electronics
  • Weapons Technologies

DTIC Thesaurus Topics

  • Acids
  • Acroleins
  • Aldehydes
  • Alkanes
  • Alkenes
  • California
  • Chemical Synthesis
  • Chemistry
  • Hydrolysis
  • Infrared Spectra
  • Military Research
  • New York
  • Organic Chemistry
  • Organosilicon Compounds
  • Plastic Explosives
  • Spectra
  • Universities

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry