Heat Capacities of H2O + H2O2, and H2O + N2H4, Binary Solutions; Isolation of a Singular Component for C sub p of Supercooled Water.

Abstract

In an effort to examine further the suggestion that anomalies in the properties of supercooled water reflect the approach to a thermodynamic singularity in the vicinity of -45 C, an attempt has been made to separate the total heat capacity of water into 'anomalous' and 'normal' components. The basis for such a separation used here is extrapolation to zero solute content of C sub p of binary aqueous solutions from which the low temperature anomalies have disappeared. We have studied two closely related systems based on the second components H2O2 and N2H4.

Open PDF

Document Details

Document Type
Technical Report
Publication Date
Feb 01, 1980
Accession Number
ADA081937

Entities

People

  • C. A. Angell
  • M. Oguni

Organizations

  • Purdue University

Tags

Communities of Interest

  • Energy and Power Technologies
  • Weapons Technologies

DTIC Thesaurus Topics

  • Aqueous Solutions
  • Chemical Synthesis
  • Chemistry
  • Emulsions
  • Glass
  • Glass Transition Temperature
  • Heat Capacity
  • Heat Energy
  • High Pressure
  • Isotherms
  • Liquids
  • Low Temperature
  • Mean Field Theory
  • Measurement
  • Military Research
  • New York
  • Transition Temperature

Readers

  • Analytical Chemistry
  • Mathematics or Statistics
  • Theoretical Analysis.