Optical Detection of Magnetic Resonance in Semiconductors.

Abstract

This report describes work on compound semiconductors using spin sensitive optical polarization and photoconductivity. Since the grant was awarded in February 1979 the spectrometer has been redesigned to give greater versatility and sensitivity. Some of the design features have been implemented and tested to show that theoretical advantages are indeed matched by experiment. The experiments so far attempted have been concerned with CdTe and GaAs:Cr. For CdTe, recombination luminescence following band gap excitation has been shown to be due to recombination processes involving donor states with g(D) = 1.61 and acceptors of g(A) = 1.35. The spectral dependence of these resonances show that the recombination is complex involving excitons trapped at neutral donors and neutral acceptors as well as holes trapped at neutral donors. The advantage of applying spin sensitive photoconductivity is readily apparent in experiments using band gap excitation in CdTe. When used for semi-insulating GaAs:Cr one remarkably observes the (5)T(2) ground state resonance even when excited with photons of energy less than one half the band gap energy. In fact spectral dependence of this resonance shows most of the sharp vibronic features of the (5)T(2) to (5)A(2) absorption band. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jan 01, 1980
Accession Number
ADA082629

Entities

People

  • Brian Henderson

Organizations

  • Trinity College Dublin

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Absorption
  • Band Gaps
  • Charge Carriers
  • Compound Semiconductors
  • Detection
  • Electrons
  • Energy Bands
  • Energy Levels
  • Excitation
  • Ground State
  • Instrumentation
  • Luminescence
  • Magnetic Resonance
  • Optical Detection
  • Polarization
  • Resonance
  • Semiconductors

Fields of Study

  • Materials science

Readers

  • Quantum spin resonance or Electron Paramagnetic Resonance spectroscopy.
  • Semiconductor Device Technology

Technology Areas

  • Microelectronics