Relationships between Radiative Properties and Mass Content of Phosphoric Acid, HC, Petroleum Oil, and Sulfuric Acid Military Smokes.

Abstract

The tactical effectiveness of military electro-optical devices such as the forward looking infrared or high energy laser (HEL) systems requires a knowledge of the extinction (absorption and scattering) by the intervening atmosphere. In the case of intentionally produced obscurants such as smokes, a quantitative assessment of these effects generally requires knowledge of the size distribution and concentration of the particles. A relation between the radiative properties of smoke particles and their mass content, even if it is an approximate one, would reduce the complexity of this assessment. One would then only need to know the spacial distribution of the mass content of the smoke particles rather than the details of their particle size distributions and number concentrations. In this report, a linear relation, independent of particle size distribution, between aerosol volume extinction coefficient and mass content is derived and applied to several military smokes: solutions of orthophosphoric acid in water, zinc chloride in water (HC smoke), diesel fuel, fog oil, and sulfuric acid smoke. Comparison of the theoretical extinction-mass relation with infrared (IR) transmission measurements of Milham (1976), Milham et al (1977), and Carlon et al (1977) shows good agreement (generally within 30 percent) between theory and measurement for the highly absorbing phosphoric acid and sulfuric acid smokes , but only fair-to-poor agreement (up to factors of 2.5 to 10 differences) for weakly absorbing HC and fog oil smokes.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1980
Accession Number
ADA084941

Entities

People

  • R. G. Pinnick
  • S. G. Jennings

Organizations

  • Atmospheric Sciences Laboratory

Tags

Communities of Interest

  • Biomedical
  • Sensors
  • Space
  • Weapons Technologies

DTIC Thesaurus Topics

  • Absorption Coefficients
  • Artillery
  • Atmospheric Sciences
  • Detectors
  • Diesel Fuels
  • Efficiency
  • Materials
  • Measurement
  • Military Research
  • Optical Phenomena
  • Optical Properties
  • Optics
  • Physics Laboratories
  • Radiation
  • Refractive Index
  • Test And Evaluation
  • Water Vapor

Readers

  • Aerosol Science/Aerosol Physics
  • Analytical Chemistry
  • Spectroscopy.

Technology Areas

  • Directed Energy