The Role of Oxygen in Gun Barrel Erosion and Cracking. A Shock Tube Gun Investigation

Abstract

Experiments to determine the individual contributors to gun barrel erosion in an oxidizing atmosphere were conducted in the Shock Tube Gun (STG), a ballistic compressor, designed and developed by Calspan Corporation. This facility can compress mixtures of pure gases and can generate flow conditions and cycle times similar to those experienced in large caliber guns. Tests were conducted with a mixture of argon and nitrogen to define the threshold erosion for an inert baseline. Small concentration of oxygen were substituted for nitrogen in the mix to quantify the oxidation effect. Subsequently, tests were conducted with various gas mixtures containing carbon dioxide, which dissociates to produce oxygen when compressed to high temperatures. The basic oxidation effect was observed to be nearly linear increase in erosion with oxygen concentration. A corresponding shift in the erosion threshold to less severe convective heating conditions was observed in response to surface chemistry. A similar effect was observed for carbon dioxide mixture where erosion was correlated in terms of the equilibrium concentration of oxygen at peak pressure. Surface cracking was observed and found to be most severe near the erosion threshold where the oxide layer was thickest. A white layer was observed in tests with oxygen in the absence of carbon dioxide.

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Document Details

Document Type
Technical Report
Publication Date
Apr 01, 1980
Accession Number
ADA085720

Entities

People

  • C. C. Morphy
  • E. B. Fisher

Organizations

  • Calspan

Tags

Communities of Interest

  • Weapons Technologies

DTIC Thesaurus Topics

  • Artillery
  • Boundary Layer
  • Carbon Dioxide
  • Carbon Monoxide
  • Chemical Elements
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Crystal Structure
  • Dielectric Gases
  • Gun Barrels
  • Heat Transfer
  • Mach Number
  • Surface Chemistry
  • Surface Temperature
  • Thermal Properties
  • Thermodynamics

Readers

  • Combustion and Flow Dynamics.
  • Electrochemical Engineering/ Fuel Cell Technologies
  • Surface Engineering/Surface Coating Technology.