The Synthesis and Reactions of 2,4-Ditertiarybutyl-3-Chloro-1-Lambda(6)-Thia-2,4-Diaza-3-Phosphetidine-1,1-Dioxide, A Heterocycle Containing Nitrogen, Sulfur, and Tricoordinate Phosphorus.

Abstract

A new four-membered nitrogen-sulfur-phosphorus ring of composition O2S(t-BuN)2PCl has been prepared by the action of PCl3 on the sulfamide, (t-BuNH)2 SO2 in the presence of Et3N and characterized by elemental analysis, and NMR, IR, and mass spectroscopy. Reaction of the title compound with SbF3 and Me3SiNMe2 afforded the 3-fluoro and 3-dimethylamino derivatives, O2S(t-BuN)2PF and O2S(t-BuN)2PNMe, respectively, and treatment with sodium in n-octane produced the diphosphine, (O2S(t-BuN)2P)2. Treatment of the thiadiazaphosphetidine ring with Fe2(CO)9 afforded the phosphorus-iron bonded complex O2S(t-BuN)2P(Cl)Fe(CO)4. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jun 16, 1980
Accession Number
ADA085960

Entities

People

  • Alan H. Cowley
  • Herbert W. Roesky
  • Sushil K. Mehrotra

Organizations

  • University of Texas at Austin

Tags

Communities of Interest

  • Air Platforms
  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Chemical Shifts
  • Chemical Synthesis
  • Chemistry
  • Classification
  • Electrons
  • Ground State
  • Inorganic Chemistry
  • Low Temperature
  • Mass Spectra
  • Mass Spectroscopy
  • Materials
  • Military Research
  • Physical Properties
  • Security
  • Spectra
  • Spectroscopy
  • Vacuum Distillation

Fields of Study

  • Chemistry

Readers

  • Organic Chemistry