Aqueous Trifluoromethanesulfonic Acid Fuel Cells.

Abstract

Subscale hydrogen-air fuel cells were successfully operated with 6M TFMSA as the electrolyte at temperatures as high as 60 C. The fuel cell performance was enhanced over similarly loaded electrodes in H3PO4 due to the apparent improved kinetics for the oxygen reduction reaction. A variety of unsupported and supported Pt electrocatalysts could be effectively utilized. TFMSA fuel cells could be operated stably for periods as long as 3000 hours if water balance was maintained. Activity coefficients calculated by the van Laar equations were utilized to predict water partial pressures of dilute TFMSA solutions. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Dec 01, 1979
Accession Number
ADA086579

Entities

People

  • Michael George

Tags

Communities of Interest

  • Energy and Power Technologies

DTIC Thesaurus Topics

  • Air Flow
  • Boiling Point
  • Cells
  • Chemistry
  • Dielectric Gases
  • Electrodes
  • Energy
  • Fuel Cells
  • Glass Fibers
  • Materials
  • Materials Processing
  • Materials Science
  • Partial Pressure
  • Phosphoric Acid Fuel Cells
  • Silicon Carbide
  • Vapor Phases
  • Vapor Pressure

Fields of Study

  • Chemistry

Readers

  • Analytical Chemistry
  • Electrochemical Engineering/ Fuel Cell Technologies

Technology Areas

  • Biotechnology
  • Microelectronics