Quantum Mechanical Studies of Molecular Hyperpolarizabilities.

Abstract

The objectives of this effort are threefold: (I) Develop state-of-the-art quantum mechanical methods to predict, from first principles, hyperpolarizabilities of atoms and molecules; (II) Determine why previous theoretical calculations have not been able to even provide order of magnitude estimates of experimental hyperpolarizabilities; and (III) Apply the quantum mechanical techniques developed in this work to predict hyperpolarizabilities and non-linear susceptibilities for a number of atoms and molecules of interest. This effort will provide complementary information to on-going experimental efforts directed toward obtaining hyperpolarizabilities.

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Document Details

Document Type
Technical Report
Publication Date
Apr 30, 1980
Accession Number
ADA086662

Entities

Organizations

  • Battelle Memorial Institute

Tags

DTIC Thesaurus Topics

  • Charge Density
  • Computational Science
  • Computations
  • Computer Programs
  • Demographic Cohorts
  • Determinants (Mathematics)
  • Difference Equations
  • Differential Equations
  • Electric Fields
  • Electrons
  • Elements
  • Frequency
  • Molecules
  • Perturbation Theory
  • Quantum Mechanics
  • Radiation
  • Second Harmonic Generation

Readers

  • Molecular Photonics/Laser Physics
  • Neurological Diseases/Conditions/Disorders
  • Systems Analysis and Design

Technology Areas

  • Quantum Computing