Composition and Temperature Dependence of Shear Viscosity of Hydrocarbon Mixtures

Abstract

Shear viscosities and densities have been measured from 50 C to as low as -56 C for five C10 hydrocarbons: n-decane, n-butyl cyclohexane, cis- decalin, n-butyl benzine and 2,7-dimethyl octane and their mixtures. A literature review of theories of hydrocarbon mixture viscosities has been carried out. It is shown that previous theories, in general, cannot give a good account of the mixture viscosities over the wide temperature range covered in this study. Two simple semi-empirical equations have been developed and applied to the description of the combined composition-temperature dependence of the viscosity of both the hydrocarbons studied under the present contract and two polycyclic hydrocarbons studied under a parallel Air Force Contract. The equations assume additivity of component free volumes in the mixtures and contain no more adjustable parameters than are required to account for the viscosities of the pure hydrocarbon components.

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Document Details

Document Type
Technical Report
Publication Date
Jul 01, 1980
Accession Number
ADA088236

Entities

People

  • A. V. Lesikar
  • C. T. Moynihan
  • M. Adel-hadadi

Organizations

  • The Catholic University of America

Tags

Communities of Interest

  • Energy and Power Technologies
  • Materials and Manufacturing Processes

DTIC Thesaurus Topics

  • Accuracy
  • Alkanes
  • Aromatic Hydrocarbons
  • Chemistry
  • Coefficients
  • Cyclic Hydrocarbons
  • Equations
  • Free Energy
  • Hydrocarbon Fuels
  • Hydrocarbons
  • Isotherms
  • Measurement
  • Molecular Dynamics
  • Molecular Weight
  • Thermodynamics
  • Transitions
  • Viscosity

Readers

  • Computational Modeling and Simulation
  • Petroleum Engineering