Electron Paramagnetic Resonance Spectroscopy of Vanadium (IV) Complexes and Related Species.

Abstract

The report details the successful application of e.p.r. spectroscopy to the study of vanadium(IV) oxohalide complexes. In particular, it has proven an invaluable structural tool for relating the structure of a complex in an amorphous or polycrystalline sample to that of the same complex in solution. Moreover, solution studies by e.p.r. have revealed previously unsuspected dissociation and displacement phenomena for complexes of the type (VOX2Ln) (X=C1 or Br, L=mono- or bi-dentate ligand), which means that many literature reports need to be reexamined. A comprehensive literature survey is included. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Jul 27, 1980
Accession Number
ADA088311

Entities

People

  • Kenneth R. Seddon

Organizations

  • University of Oxford

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Alkanes
  • Chemical Synthesis
  • Chemistry
  • Computer Programs
  • Crystal Structure
  • Electron Paramagnetic Resonance
  • Electron Spin Resonance
  • Energy Bands
  • Fungi
  • Inorganic Chemistry
  • Magnetic Fields
  • Magnetic Properties
  • Paramagnetic Resonance
  • Quantum Properties
  • Spectra
  • Spectroscopy
  • Spin Resonance

Readers

  • Materials Science and Engineering.
  • Organic Chemistry
  • Theoretical Analysis.

Technology Areas

  • Microelectronics
  • Microelectronics - Graphene