Testing Iodized Activated Carbon Filters with Non-Radio Active Methyl Iodide.

Abstract

Iodized carbons, impregnated with KIx(KI + xI2), were evaluated for trapping methyl iodide-127. In this method the complete effluent of the carbon is sampled and analyzed continuously. In contrast, the RDT-M16 test procedure counts the carbon and the back-up beds for the accumulated 131 species and no information is obtained for the interaction of the large amount of carrier methyl iodide-127 with the iodized charcoal. The test apparatus to measure the penetration of methyl iodide-127 is described and the calibration procedures are detailed. Results are given for the penetration of methyl iodide-127 through new activated carbons, carbons in service, and exhausted carbons withdrawn from service. The reduction in trapping efficiency with service is accompanied by the development of a maximum in the concentration of methyl iodide-127 during the air purge after the dose period. This behavior has escaped notice with methyl iodide-131 due to the way that test is made. The chromatographic holdup of methyl iodide-127 by carbons in service, together with the subsequent slow desorption step, could result in a dilution of the penetration iodine to acceptable levels under some conditions encountered in plant filter operations.

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Document Details

Document Type
Technical Report
Publication Date
May 30, 1980
Accession Number
ADA088666

Entities

People

  • James B. Romans
  • Victor R. Deitz

Organizations

  • United States Naval Research Laboratory

Tags

Communities of Interest

  • Biomedical

DTIC Thesaurus Topics

  • Air Flow
  • Base Lines
  • Chemical Reactions
  • Chemical Synthesis
  • Chemistry
  • Desorption
  • Detectors
  • Electron Capture
  • Elements
  • Environmental Pollutants
  • Isotope Exchange
  • Isotopes
  • Measurement
  • Military Research
  • Molecular Weight
  • Standards
  • Test Equipment

Readers

  • Aerosol Science/Aerosol Physics
  • Internal Combustion Engine (ICE) Technology.
  • Organic Chemistry