A Diglyme Adduct of Tin(IV) Chloride Formed on Drying Aromatic Solvents by the Benzophenone Ketyl/Potassium Metal Method,

Abstract

Use of diglyme (diethyleneglycoldimethylether) for solubilization in the benzophenone ketyl/potassium metal method for drying and deoxygenating aromatic solvents can result in contamination of the distilled solvent with subsequent formation of adducts with Lewis acids. The diglyme adduct of tin(IV) chloride is isolated, and the magnitude of its tin-119m Mossbauer Quadrupole Splitting interpreted in terms of its structure. (Author)

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Document Details

Document Type
Technical Report
Publication Date
Aug 15, 1980
Accession Number
ADA089044

Entities

People

  • Jerold J. Zuckerman
  • W. A. Gustavson

Organizations

  • University of Oklahoma

Tags

Communities of Interest

  • Advanced Electronics

DTIC Thesaurus Topics

  • Chemical Analysis
  • Chemical Compounds
  • Chemistry
  • Chlorides
  • Dipole Moments
  • Distortion
  • Infrared Spectra
  • Lewis Acids
  • Mass Spectra
  • Metals
  • Oklahoma
  • Organic Chemistry
  • Potassium
  • Resonance
  • Spectra
  • Spectroscopy
  • Universities

Fields of Study

  • Chemistry

Readers

  • Agricultural Chemistry/Soil Science
  • Organic Chemistry