Organometallic Phosphazenes: Synthesis and Rearrangement of Propynyl and Propadienyl Cyclotriphosphazenes.
Abstract
Copper- or lithiophosphazene anions react with prop-2-ynyl bromide with the attachment fo the prop-2-ynyl group to the ring. Subsequent rearrangements yielded prop-1,2-dienyl or prop-1-ynyl derivatives. The mechanism of these reactions is discussed. These model reactions are of considerable significance for the analogous polymeric substitutions. (Author)
Document Details
- Document Type
- Technical Report
- Publication Date
- Sep 22, 1980
- Accession Number
- ADA089694
Entities
People
- Harry R. Allcock
- P. J. Harris
- R. A. Nissan
Organizations
- Pennsylvania State University